Książka Transition Metal Nanoparticles Engelbert Redel

Transition Metal Nanoparticles

Synthesis, Characterization, Stabilization and Functionalization of different Transition Metal Nanoparticles in Ionic Liquids (ILs).

Język: Angielski
Oprawa: Miękka
Dostępność: Dostępna u dostawcy
Wysyłamy za 8-11 dni
199.76
This work contain the synthesis, characterization, stabilization and functionalization of different...

Informacje o książce

Język
Angielski
Oprawa
Książka - Miękka
Data wydania
2009
strony
112
EAN
9783838110264
ISBN
3838110269
Enbook ID
07063952
Waga
159
Wymiary
152 x 229 x 6

Pełny opis

This work contain the synthesis, characterization, stabilization and functionalization of different transition Metal Nanoparticles (M-NPs; with M = Cr, Mo, W, Fe, Ru, Os, Co, Rh, Ir, Ag & Au) in Ionic Liquids (ILs). The ILs act as non-surfactant, or weakly coordinating supramolecular network for the kinetic stabilization of the M-NPs. The size of different transitions M-NPs was shown to depend upon the choice of the IL (especially the anion therein), which was demonstrated using different methods and synthesis procedures. Characterization of the dispersed transitions nanoparticles was done by TEM/HRTEM, TED, XRPD, and DLS. Furthermore, NMR spectroscopy and Density Functional Theory (DFT) calculations were done to understand the interactions and stabilization mechanisms of dispersed transition M-NPs in ILs. The DFT calculations and dynamic NMR studies support strongly IL/anion···Au-NPs interactions and a dynamic anion stabilization around M-NP clusters. This mechanistic understanding was crucial for a deep insight into the interaction processes between the IL-network and the naked metal nanoclusters.

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