Książka XUV Pump-Probe Experiments on Diatomic Molecules Kirsten Schnorr

XUV Pump-Probe Experiments on Diatomic Molecules

Tracing the Dynamics of Electron Rearrangement and Interatomic Coulombic Decay

Język: Angielski
Oprawa: Twarda
Dostępność: Dostępna u dostawcy
Wysyłamy za 10-13 dni
428.07
This book explores the relaxation dynamics of inner-valence-ionized diatomic molecules on the basis...

Informacje o książce

Język
Angielski
Oprawa
Książka - Twarda
Data wydania
2014
strony
191
EAN
9783319121383
ISBN
3319121383
Enbook ID
06841783
Waga
4321
Wymiary
155 x 235 x 16

Pełny opis

This book explores the relaxation dynamics of inner-valence-ionized diatomic molecules on the basis of extreme-ultraviolet pump-probe experiments performed at the free-electron laser (FEL) in Hamburg. Firstly, the electron rearrangement dynamics in dissociating multiply charged iodine molecules is studied in an experiment that made it possible to access charge transfer in a thus far unexplored quasimolecular regime relevant for plasma and chemistry applications of the FEL. Secondly the lifetime of an efficient non-radiative relaxation process that occurs in weakly bound systems is measured directly for the first time in a neon dimer (Ne 2 ). Interatomic Coulombic decay (ICD) has been identified as the dominant decay mechanism in inner-valence-ionized or excited van-der-Waals and hydrogen bonded systems, the latter being ubiquitous in all biomolecules. The role of ICD in DNA damage thus demands further investigation, e.g. with regard to applications like radiation therapy.

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