Ionic liquids, use and specific task as solvent in catalytic reaction

Name: Ionic liquids, use and specific task as solvent in catalytic reaction
Brand: LAP Lambert Academic Publishing
SKU: 9783838334066
Price: 221.76 PLN
Availability: InStock

Autor: Thiebaut Gutel

Język:

Oprawa: Miękka

Wydawca: LAP Lambert Academic Publishing

Dostępność: Dostępna u dostawcy

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Ionic liquids, associations of organic cations and anions, are media organized over several nanomete...

Informacje o książce

Autor

Thiebaut Gutel

Język

Angielski

Oprawa

Książka - Miękka

Data wydania

2010

strony

144

EAN

9783838334066

Enbook ID

06949679

Wydawca

LAP Lambert Academic Publishing

Waga

233

Wymiary

150 x 220 x 8

Pełny opis

Ionic liquids, associations of organic cations and anions, are media organized over several nanometers and present a segregation in polar and nonpolar microdomains. As they are used as solvents for catalytic reactions, they can induce specific solvation phenomena. For instance, ion exchange reactions in some catalytic systems and some py-cation interactions with unsaturated hydrocarbons have been observed by NMR. The consequences of the specific solvation on hydrogenation reactions have been studied. It appears that the stronger the interactions between IL and reactants are, the slower the reactions are. The presence of nonpolar and polar microdomains leads to a preferential solvation of organometallic complexes in apolar pockets that enable the use of these media as supramolecular matrices and to control the crystal growth of metal nanoparticles generated in situ according to the alkyl chain length and the temperature.

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Ionic liquids, use and specific task as solvent in catalytic reaction

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